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List 2012-14

 

Risk Pharses (R)

  • R1 - Explosive When dry.
  • R2 - Risk of explosion by shock, friction, fire or other sources of ignition.
  • R3 - Extreme risk of explosion by shock, friction, fire or other sources of ignition.
  • R4 - Forms very sensitive explosive metallic compounds.
  • R5 - Heating may cause an explosion.
  • R6 - Explosive with or without contact with air.
  • R7 - May cause fire.
  • R8 - Contact with combustible material may cause fire.
  • R9 - Explosive when mixed with combustible material.
  • R10 - Flammable.
  • R11 - Highly flammable.
  • R12 - Extremely flammable.
  • R13 - Extremely flammable liquified gas.
  • R14 - Reacts violently with water.
  • R15 - Contact with water liberates highly flammable gases.
  • R16 - Explosive when mixed with oxidizing substances.
  • R17 - Spontaneously flammable in air.
  • R18 - In use, may from flammable/explosive vapour-air mixture.
  • R19 - May form explosive peroxides.
  • R20 - Harmful by inhalation.
  • R21 - Harmful in contact with skin
  • R22 - Harmful if swallowed.
  • R23 - Toxic by inhalation.
  • R24 - Toxic in contact with skin.
  • R25 - Toxic if swallowed.
  • R26 - Very toxic by inhalation.
  • R27 - Very toxic in contact with skin.
  • R28 - Very toxic if swallowed.
  • R29 - Contact with water liberates toxic gas.
  • R30 - Can become highly flammable in use.
  • R31 - Contact with acids
  • R32 - Contact with acids liberates very toxic gas.
  • R33 - Danger of cumulative effects.
  • R34 - Causes burns
  • R35 - Causes severe burns.
  • R36 - Irritating to eyes.
  • R37 - Irritating to respiratory system.
  • R38 - Irritating to skin.
  • R39 - Danger of very serious irreversible effects.
  • R40 - Possible risk of irreversible effects.
  • R41 - Risk of serious damage to eyes.
  • R42 - May cause sensitization by inhalation.
  • R43 - May cause sensitization by skin contact.
  • R44 - Risk of explosion if heated under confinement.
  • R45 - May cause cancer.
  • R46 - May cause heritable genetic damage.
  • R47 - May cause birth defects.
  • R48 - Danger of serious damage to health by prolonged exposure.
  • R49 - May cause cancer by inhalation.
  • R50 - Very toxic to aquatic organisms.
  • R51 - Toxic to aquatic organisms.
  • R52 - Harmful to aquatic organisms.
  • R53 - May cause long-term adverse effects in the aquatic environment.
  • R54 - Toxic to flora.
  • R55 - Toxic to fauna.
  • R56 - Toxic to soil organisms.
  • R57 - Toxic to bees.
  • R58 - May cause long-term adverse in the environment.
  • R59 - Dangerous for the ozone layer


 

Combination Riskphrases

  • R14/15 - Reacts violently with water liberating highly flammable gases.
  • R15/29 - Contact with water liberates toxic, highly flammable gas.
  • R20/21 - Harmful by inhalation and in contact with skin.
  • R20/22 - Harmful by inhalation and if swallowed.
  • R21/22 - Harmful in contact with skin and if swallowed.
  • R20/21/22 - Harmful by inhalation, in contact with skin if swallowed.
  • R23/24 - Toxic by inhalation and in contact with skin.
  • R23/25 - Toxic by inhalation and if swallowed.
  • R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed
  • R24/25 - Toxic in contact with skin and if swallowed.
  • R26/27 - Very toxic by inhalation and in contact with skin.
  • R26/28 - Very toxic by inhalation and if swallowed.
  • R26/27/28 - Very toxic by inhalation, in contact with skin and if swallowed.
  • R27/28 - Very toxic in contact with skin and if swallowed.
  • R36/37 - Irritating to eyes and respiratory system.
  • R36/38 - Irritating to eyes and skin
  • R36/37/38 - Irritating to eyes, respiratory system and skin.
  • R37/38 - Irritating to respiratory system and skin.
  • R39/23 - Toxic : danger of very serious irreversible effects through inhalation.
  • R39/24 - Toxic : danger of very serious irreversible effects in contact with skin.
  • R39/25 - Toxic : danger of very serious irreversible effects if swallowed.
  • R39/23/24 - Toxic : danger of very serious irreversible effects through inhalation and in contact with skin.
  • R39/23/25 - Toxic : danger of very serious irreversible effects through inhalation and if swallowed.
  • R39/24/25 - Toxic : danger or very serious irreversible effects in contact with skin and if swallowed.
  • R39/23/24/25 - Toxic : danger of very serious irreversible effect through inhalation, in contact with skin and if swallowed.
  • R39/26 - Very toxic : danger of very serious irreversible effects through inhalation.
  • R39/27 - Very toxic : danger of very serious irreversible effects in contact with skin.
  • R39/28 - Very toxic : danger of very serious irreversible effects if swallowed.
  • R39/26/27 - Very toxic : danger of very serious irreversible effects through inhalation and in contact with skin.
  • R39/26/28 - Very toxic : danger of very serious irreversible effects through inhalation and if swallowed
  • R39/27/28 - Very toxic : danger of very serious irreversible effects in contact with skin and if swallowed.
  • R39/26/27/28 - Very toxic : danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
  • R40/20 - Harmful : possible risk of irreversible effects through inhalation.
  • R40/21 - Harmful : possible risk of irreversible effects in contact with skin.
  • R40/22 - Harmful : possible risk of irreversible effects if swallowed.
  • R40/20/21 - Harmful : possible risk of irreversible effects through inhalation and in contact with skin.
  • R40/21/22 - Harmful : possible risk of irreversible effects in contact with skin and if swallowed.
  • R40/20/21/22 - Harmful : possible risk of irreversible effects through inhalation in contact with skin and if swallowed.
  • R42/43 - May cause sensitization by inhalation and skin contact.
  • R48/20 - Harmful : danger of serious damage to health by prolonged exposure through inhalation.
  • R48/21 - Harmful : danger of serious damage to health by prolonged exposure in contact with skin.
  • R48/22 - Harmful : danger of serious damage to health by prolonged exposure if swallowed
  • R48/20/21 - Harmful : danger of serious damage to health by prolonged exposure through inhalation and in contact with skin.
  • R48/20/22 - Harmful : danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
  • R48/21/22 - Harmful : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
  • R48/20/21/22 - Harmful : danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
  • R48/23 - Toxic : danger of serious damage to health by prolonged exposure through inhalation.
  • R48/24 - Toxic : danger of serious damage to health by prolonged exposure in contact with skin
  • R48/25 - Toxic : danger of serious damage to health by prolonged exposure if swallowed.
  • R48/23/24 - Toxic : danger of serious damage to health by prolonged exposure through inhalation and in contact with skin.
  • R48/23/25 - Toxic : danger of serious damage to health by prolonged exposure through inhalation & of swallowed.
  • R4824/25 - Toxic : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
  • R48/23/24/25 - Toxic : danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
 

Safety Pharses (S)

  • S1 - Keep locked up
  • S2 - Keep out of reach of children.
  • S3 - Keep in cool place.
  • S4 - Keep away from living quarters.
  • S5 - Keep contents under.. (appropriate liquid to be specified by the manufacturer)
  • S6 - Keep under ... (inert gas to be specified by the manufacturer)
  • S7 - Keep container tightly closed.
  • S8 - Keep container dry.
  • S9 - Keep container in a well ventilated place.
  • S12 - Do not keep the container sealed.
  • S13 - Keep away from food, drink and animal feeding stuffs.
  • S14 - Keep away from... (incompetable materials to be indicated by the manufacturer)
  • S15 - Keep away from heat.
  • S16 - Keep away from sources of ignition No smoking.
  • S17 - Keep away from combustible material.
  • S18 - Handle and open container with care.
  • S20 - When using do not eat or drink.
  • S21 - When using do not smoking.
  • S22 - Do not breathe dust.
  • S23 - Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
  • S24 - Avoid contact with skin.
  • S25 - Avoid contact with eyes.
  • S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
  • S27 - Take off immediately all contaminated clothing.
  • S28 - After contact with skin, wash immediately with plenty of..(to be specified by the manufacturer)
  • S29 - Do not empty into drains.
  • S30 - Never add water to this product.
  • S33 - Take precautionary measures against static discharges.
  • S34 - Avoid shock and friction.
  • S35 - This material and its container must be disposed of in a safe way.
  • S36 - Wear suitable protective clothing.
  • S37 - Wear suitable gloves.
  • S38 - In case of insufficient Ventilation wear suitable respiratory equipment.
  • S39 - Wear eye/face protection.
  • S40 - To clean the floor and all objects contaminated by this material use... (to be specified by the manufacturer).
  • S41 - In case of fire and/or explosion do not breathe fumes.
  • S42 - During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified).
  • S43 - In case of fire, use..(indicated in the space the precise type of fire fighting equipment. If water increases the risk, add-never use water).
  • S44 - If you feel unwell, seek, medical advice (show the label where possible).
  • S45 - In case of accident or if you feel unwell., seek medical advice immediately (show the label where possible)
  • S46 - If swallowed seek medical advice immediately and show this container or label
  • S47 - Keep at temperature no exceeding.. C (to be specified by the manufacturer)
  • S48 - Keep wetted with ... (appropriate material to be specified by the manufacturer)
  • S49 - Keep only in the original container.
  • S50 - Do not mix with .. (to be a specified by the manufacturer).
  • S51 - Use only in well ventilated areas.
  • S52- Not recommended for interior use on large surface areas.
  • S53 - Avoid exposure - obtain special instructions before use instruction.
  • S54 - Obtain the consent of pollution control authorities before discharging to wastewater treatment plants.
  • S55 - Treat using the best available techniques before discharge into drains or the aquatic environment.
  • S56 - Do not discharge into drains or the environment, dispose to an authorised waste collection point.
  • S57 - Use appropriate containment to avoid environmental contamination.
  • S58 - To be disposed of as hazardous waste.
  • S59 - Refer to manufacturer/supplier for information on recovery/recycling.
  • S60 - This material and/or its container must be disposed of as hazardous waste.

Combination Safety Phrases :

  • S1/2 - Keep locked up and out of reach of children.
  • S3/7/9 - Keep container tightly closed in a cool well-ventillated place.
  • S3/9 - Keep in a cool well-ventilated pace.
  • S3/9/14 - Keep in a cool, well-ventilated place away from ... (incompatible material to be indicated by the manufacturer)
  • S3/914/49 - Keep only in the original container in a cool wellventilated place away from ... (incompatible materials to be indicated by the manufacturer).
  • S3/9/49 - Keep only in the original container in a cool wellventilated place.
  • S3/14 - Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer).
  • S7/8 - Keep container tightly closed and dry.
  • S7/9 - Keep container tightly closed and in well-ventilated place.
  • S20/21 - When using do not eat, drink or smoke.
  • S24/25 - Avoid contact with skin and eyes.
  • S36/37 - Wear suitable protective clothing and gloves.
  • S36/39 - Wear suitable protective clothing and eye/face protection.
  • S37/39 - Wear suitable gloves and eye/face protection.
  • S36/37/39 - Wear suitable protective clothing, gloves and eye/face pro
  • S47/49 - Keep only in the original container at temperature not exceeding .. C (to be specified by the manufacturer).

F :

  • 1 - Sensitive to air and humidity.
  • 2 - Sensitive air and CO
  • 3 - Hygroscopic
  • 4 - Do not heat over ... C
  • 5 - Dry material may explode.
  • 6 - Reacts with acids.
  • 7 - Keep under CO.
  • 8 - Photosensitive.
  • 9 - Keep under nitrogen.
  • 10 - Keep under argon
  • 11 - keep under inert gas.
  • 12 - Shake before use
  • 13 - Malodorous.
  • 14 - Carefully observe warning label.
  • 15 - Short shelf life.
  • 16 - Decomposes easily.
  • 17 - May decompose by explosion.
  • 18 - Must be handled by instructed people only.
  • 19 - Lachrymator.
  • 20 - Not to be swallowed.
  • 21 - Sensitive to humidity.
  • 22 - Keep dust-free in the dark
  • 23 - Sensitive to air.
  • 24 - Spontaneously flammable with alcohol.
  • 25 - Keep under CO.
  • 26 - Before distillation test for absence of peroxides.
  • 27 - Cool before opening.
  • 28 - May become cloudy (Polyformaldehyde).
  • 29 - Spontaneously flammable when dry.
  • 30 - Sediment inavodiable.
  • 31 - Do not puncture.
  • 32 - Avoid contact with heavy metal salts esp. iron salts.
  • 33 - Causes fall in blood pressure.
  • 34 - Sensitive to CO.