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Risk Pharses (R)
- R1 - Explosive When dry.
- R2 - Risk of explosion by shock, friction, fire or other sources of ignition.
- R3 - Extreme risk of explosion by shock, friction, fire or other sources of ignition.
- R4 - Forms very sensitive explosive metallic compounds.
- R5 - Heating may cause an explosion.
- R6 - Explosive with or without contact with air.
- R7 - May cause fire.
- R8 - Contact with combustible material may cause fire.
- R9 - Explosive when mixed with combustible material.
- R10 - Flammable.
- R11 - Highly flammable.
- R12 - Extremely flammable.
- R13 - Extremely flammable liquified gas.
- R14 - Reacts violently with water.
- R15 - Contact with water liberates highly flammable gases.
- R16 - Explosive when mixed with oxidizing substances.
- R17 - Spontaneously flammable in air.
- R18 - In use, may from flammable/explosive vapour-air mixture.
- R19 - May form explosive peroxides.
- R20 - Harmful by inhalation.
- R21 - Harmful in contact with skin
- R22 - Harmful if swallowed.
- R23 - Toxic by inhalation.
- R24 - Toxic in contact with skin.
- R25 - Toxic if swallowed.
- R26 - Very toxic by inhalation.
- R27 - Very toxic in contact with skin.
- R28 - Very toxic if swallowed.
- R29 - Contact with water liberates toxic gas.
- R30 - Can become highly flammable in use.
- R31 - Contact with acids
- R32 - Contact with acids liberates very toxic gas.
- R33 - Danger of cumulative effects.
- R34 - Causes burns
- R35 - Causes severe burns.
- R36 - Irritating to eyes.
- R37 - Irritating to respiratory system.
- R38 - Irritating to skin.
- R39 - Danger of very serious irreversible effects.
- R40 - Possible risk of irreversible effects.
- R41 - Risk of serious damage to eyes.
- R42 - May cause sensitization by inhalation.
- R43 - May cause sensitization by skin contact.
- R44 - Risk of explosion if heated under confinement.
- R45 - May cause cancer.
- R46 - May cause heritable genetic damage.
- R47 - May cause birth defects.
- R48 - Danger of serious damage to health by prolonged exposure.
- R49 - May cause cancer by inhalation.
- R50 - Very toxic to aquatic organisms.
- R51 - Toxic to aquatic organisms.
- R52 - Harmful to aquatic organisms.
- R53 - May cause long-term adverse effects in the aquatic environment.
- R54 - Toxic to flora.
- R55 - Toxic to fauna.
- R56 - Toxic to soil organisms.
- R57 - Toxic to bees.
- R58 - May cause long-term adverse in the environment.
- R59 - Dangerous for the ozone layer
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Combination Riskphrases
- R14/15 - Reacts violently with water liberating highly flammable gases.
- R15/29 - Contact with water liberates toxic, highly flammable gas.
- R20/21 - Harmful by inhalation and in contact with skin.
- R20/22 - Harmful by inhalation and if swallowed.
- R21/22 - Harmful in contact with skin and if swallowed.
- R20/21/22 - Harmful by inhalation, in contact with skin if swallowed.
- R23/24 - Toxic by inhalation and in contact with skin.
- R23/25 - Toxic by inhalation and if swallowed.
- R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed
- R24/25 - Toxic in contact with skin and if swallowed.
- R26/27 - Very toxic by inhalation and in contact with skin.
- R26/28 - Very toxic by inhalation and if swallowed.
- R26/27/28 - Very toxic by inhalation, in contact with skin and if swallowed.
- R27/28 - Very toxic in contact with skin and if swallowed.
- R36/37 - Irritating to eyes and respiratory system.
- R36/38 - Irritating to eyes and skin
- R36/37/38 - Irritating to eyes, respiratory system and skin.
- R37/38 - Irritating to respiratory system and skin.
- R39/23 - Toxic : danger of very serious irreversible effects through inhalation.
- R39/24 - Toxic : danger of very serious irreversible effects in contact with skin.
- R39/25 - Toxic : danger of very serious irreversible effects if swallowed.
- R39/23/24 - Toxic : danger of very serious irreversible effects through inhalation and in contact with skin.
- R39/23/25 - Toxic : danger of very serious irreversible effects through inhalation and if swallowed.
- R39/24/25 - Toxic : danger or very serious irreversible effects in contact with skin and if swallowed.
- R39/23/24/25 - Toxic : danger of very serious irreversible effect through inhalation, in contact with skin and if swallowed.
- R39/26 - Very toxic : danger of very serious irreversible effects through inhalation.
- R39/27 - Very toxic : danger of very serious irreversible effects in contact with skin.
- R39/28 - Very toxic : danger of very serious irreversible effects if swallowed.
- R39/26/27 - Very toxic : danger of very serious irreversible effects through inhalation and in contact with skin.
- R39/26/28 - Very toxic : danger of very serious irreversible effects through inhalation and if swallowed
- R39/27/28 - Very toxic : danger of very serious irreversible effects in contact with skin and if swallowed.
- R39/26/27/28 - Very toxic : danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
- R40/20 - Harmful : possible risk of irreversible effects through inhalation.
- R40/21 - Harmful : possible risk of irreversible effects in contact with skin.
- R40/22 - Harmful : possible risk of irreversible effects if swallowed.
- R40/20/21 - Harmful : possible risk of irreversible effects through inhalation and in contact with skin.
- R40/21/22 - Harmful : possible risk of irreversible effects in contact with skin and if swallowed.
- R40/20/21/22 - Harmful : possible risk of irreversible effects through inhalation in contact with skin and if swallowed.
- R42/43 - May cause sensitization by inhalation and skin contact.
- R48/20 - Harmful : danger of serious damage to health by prolonged exposure through inhalation.
- R48/21 - Harmful : danger of serious damage to health by prolonged exposure in contact with skin.
- R48/22 - Harmful : danger of serious damage to health by prolonged exposure if swallowed
- R48/20/21 - Harmful : danger of serious damage to health by prolonged exposure through inhalation and in contact with skin.
- R48/20/22 - Harmful : danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
- R48/21/22 - Harmful : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
- R48/20/21/22 - Harmful : danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
- R48/23 - Toxic : danger of serious damage to health by prolonged exposure through inhalation.
- R48/24 - Toxic : danger of serious damage to health by prolonged exposure in contact with skin
- R48/25 - Toxic : danger of serious damage to health by prolonged exposure if swallowed.
- R48/23/24 - Toxic : danger of serious damage to health by prolonged exposure through inhalation and in contact with skin.
- R48/23/25 - Toxic : danger of serious damage to health by prolonged exposure through inhalation & of swallowed.
- R4824/25 - Toxic : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
- R48/23/24/25 - Toxic : danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
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Safety Pharses (S)
- S1 - Keep locked up
- S2 - Keep out of reach of children.
- S3 - Keep in cool place.
- S4 - Keep away from living quarters.
- S5 - Keep contents under.. (appropriate liquid to be specified by the manufacturer)
- S6 - Keep under ... (inert gas to be specified by the manufacturer)
- S7 - Keep container tightly closed.
- S8 - Keep container dry.
- S9 - Keep container in a well ventilated place.
- S12 - Do not keep the container sealed.
- S13 - Keep away from food, drink and animal feeding stuffs.
- S14 - Keep away from... (incompetable materials to be indicated by the manufacturer)
- S15 - Keep away from heat.
- S16 - Keep away from sources of ignition No smoking.
- S17 - Keep away from combustible material.
- S18 - Handle and open container with care.
- S20 - When using do not eat or drink.
- S21 - When using do not smoking.
- S22 - Do not breathe dust.
- S23 - Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
- S24 - Avoid contact with skin.
- S25 - Avoid contact with eyes.
- S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
- S27 - Take off immediately all contaminated clothing.
- S28 - After contact with skin, wash immediately with plenty of..(to be specified by the manufacturer)
- S29 - Do not empty into drains.
- S30 - Never add water to this product.
- S33 - Take precautionary measures against static discharges.
- S34 - Avoid shock and friction.
- S35 - This material and its container must be disposed of in a safe way.
- S36 - Wear suitable protective clothing.
- S37 - Wear suitable gloves.
- S38 - In case of insufficient Ventilation wear suitable respiratory equipment.
- S39 - Wear eye/face protection.
- S40 - To clean the floor and all objects contaminated by this material use... (to be specified by the manufacturer).
- S41 - In case of fire and/or explosion do not breathe fumes.
- S42 - During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified).
- S43 - In case of fire, use..(indicated in the space the precise type of fire fighting equipment. If water increases the risk, add-never use water).
- S44 - If you feel unwell, seek, medical advice (show the label where possible).
- S45 - In case of accident or if you feel unwell., seek medical advice immediately (show the label where possible)
- S46 - If swallowed seek medical advice immediately and show this container or label
- S47 - Keep at temperature no exceeding.. C (to be specified by the manufacturer)
- S48 - Keep wetted with ... (appropriate material to be specified by the manufacturer)
- S49 - Keep only in the original container.
- S50 - Do not mix with .. (to be a specified by the manufacturer).
- S51 - Use only in well ventilated areas.
- S52- Not recommended for interior use on large surface areas.
- S53 - Avoid exposure - obtain special instructions before use instruction.
- S54 - Obtain the consent of pollution control authorities before discharging to wastewater treatment plants.
- S55 - Treat using the best available techniques before discharge into drains or the aquatic environment.
- S56 - Do not discharge into drains or the environment, dispose to an authorised waste collection point.
- S57 - Use appropriate containment to avoid environmental contamination.
- S58 - To be disposed of as hazardous waste.
- S59 - Refer to manufacturer/supplier for information on recovery/recycling.
- S60 - This material and/or its container must be disposed of as hazardous waste.
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Combination Safety Phrases :
- S1/2 - Keep locked up and out of reach of children.
- S3/7/9 - Keep container tightly closed in a cool well-ventillated place.
- S3/9 - Keep in a cool well-ventilated pace.
- S3/9/14 - Keep in a cool, well-ventilated place away from ... (incompatible material to be indicated by the manufacturer)
- S3/914/49 - Keep only in the original container in a cool wellventilated place away from ... (incompatible materials to be indicated by the manufacturer).
- S3/9/49 - Keep only in the original container in a cool wellventilated place.
- S3/14 - Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer).
- S7/8 - Keep container tightly closed and dry.
- S7/9 - Keep container tightly closed and in well-ventilated place.
- S20/21 - When using do not eat, drink or smoke.
- S24/25 - Avoid contact with skin and eyes.
- S36/37 - Wear suitable protective clothing and gloves.
- S36/39 - Wear suitable protective clothing and eye/face protection.
- S37/39 - Wear suitable gloves and eye/face protection.
- S36/37/39 - Wear suitable protective clothing, gloves and eye/face pro
- S47/49 - Keep only in the original container at temperature not exceeding .. C (to be specified by the manufacturer).
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F :
- 1 - Sensitive to air and humidity.
- 2 - Sensitive air and CO
- 3 - Hygroscopic
- 4 - Do not heat over ... C
- 5 - Dry material may explode.
- 6 - Reacts with acids.
- 7 - Keep under CO.
- 8 - Photosensitive.
- 9 - Keep under nitrogen.
- 10 - Keep under argon
- 11 - keep under inert gas.
- 12 - Shake before use
- 13 - Malodorous.
- 14 - Carefully observe warning label.
- 15 - Short shelf life.
- 16 - Decomposes easily.
- 17 - May decompose by explosion.
- 18 - Must be handled by instructed people only.
- 19 - Lachrymator.
- 20 - Not to be swallowed.
- 21 - Sensitive to humidity.
- 22 - Keep dust-free in the dark
- 23 - Sensitive to air.
- 24 - Spontaneously flammable with alcohol.
- 25 - Keep under CO.
- 26 - Before distillation test for absence of peroxides.
- 27 - Cool before opening.
- 28 - May become cloudy (Polyformaldehyde).
- 29 - Spontaneously flammable when dry.
- 30 - Sediment inavodiable.
- 31 - Do not puncture.
- 32 - Avoid contact with heavy metal salts esp. iron salts.
- 33 - Causes fall in blood pressure.
- 34 - Sensitive to CO.
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